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Carnot Efficiency⚠ unverified

Physics / Thermodynamics · Maximum thermal efficiency of a heat engine between two reservoirs

Parameters

InputSymbolUnitDefaultDescription
T_hotThK500.0Hot reservoir temperature
T_coldTcK300.0Cold reservoir temperature
OutputSymbolUnitDescription
efficiencyηCarnot efficiency

The science & history

Understanding the Parameters

Derivation (Approaching a Proof)

For a reversible cycle exchanging $Q_h$ at $T_h$ and rejecting $Q_c$ at $T_c$, Clausius equality gives $\oint dQ_{\mathrm{rev}}/T = 0$, so $Q_h/T_h = Q_c/T_c$. First-law net work $W = Q_h - Q_c$ (magnitudes for the engine), hence

$$\eta = \frac{W}{Q_h} = 1 - \frac{Q_c}{Q_h} = 1 - \frac{T_c}{T_h}.$$

Any irreversible engine between the same reservoirs has lower $\eta$ (Kelvin–Planck / second law).

History

Sadi Carnot (1824) reasoned about ideal heat engines; absolute temperature and the modern $\eta = 1 - T_c/T_h$ form followed Kelvin and Clausius in the mid-19th century.

Related Concepts: Thermal Efficiency, Otto Efficiency, Brayton Efficiency, Rankine Efficiency, Second Law Entropy, Exergy

Notes: Registry calculator carnot-efficiency (unverified). Ideal two-reservoir limit only.

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