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Entropy Change Ideal Gas⚠ unverified

Physics / Thermodynamics · Compute the entropy change of an ideal gas between two states

Parameters

InputSymbolUnitDefaultDescription
mmkg1.0Mass of the gas
cvcv1.0Specific heat at constant volume, in joules per kilogram-kelvin (J/(kg.K))
T2T2K1.0Absolute temperature at state 2
T1T1K1.0Absolute temperature at state 1
RR1.0Specific gas constant, in joules per kilogram-kelvin (J/(kg.K))
v2v2m^3/kg1.0Specific volume at state 2
v1v1m^3/kg1.0Specific volume at state 1
OutputSymbolUnitDescription
resultΔSJ/KEntropy change, in joules per kelvin (J/K)

The science & history

Understanding the Parameters

Derivation (Approaching a Proof)

From $T\,ds = du + p\,dv$ and $du = c_v\,dT$, $p = \rho R T = R T / v$ (specific),

$$ds = c_v\frac{dT}{T} + R\frac{dv}{v}.$$

Integrate with constant $c_v$, $R$ between states 1 and 2; multiply by mass $m$ for total $\Delta S$.

History

Clausius’s entropy and ideal-gas integrations are core 19th-century thermodynamics; this $T$–$v$ formula is standard textbook material.

Related Concepts: Second Law Entropy, First Law DeltaU, Exergy Destruction, Speed Of Sound

Notes: Registry calculator entropy-change-ideal-gas (unverified). Unit bugs: $c_v$ and $R$ labelled dimensionless. Constant-$c_v$ ideal gas only.

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